基于多项式变换的参数估计方法

本文给出一种采用DPT估计SNCK信号时宽—带宽积的方法,并通过仿真该估计方法的性能与其它估计方法进行比较.首先给出SNCK信号参数估计的一般过程.为了便于计算和理论推导,根据估计出的中心频率将接收到的SNCK信号搬移到零频,从而进一步估计其它参数,如采用DPT估计SNCK信号时宽带宽积.本文将重点研究采用DPT算法估计SNCK信号值的方法.     

Inhibition of counterflow methane/air diffusion flame by water mist with varying mist diameter

In the present study, the effect of fine water mist on extinguishment of a methane–air counterflow diffusion flame was investigated to understand the underlying physics of fire extinguishment of highly stretched diffusion flame by water mist. Twin-fluid atomizers were used to generate polydisperse water mist of which Sauter mean diameters were 10, 20, 40, and 60 μm. When water mist is not added, the critical stretch rate at extinguishment is 439 s⁻¹ as compared to the theoretical value of 460 s⁻¹. For the case with water mist addition, when the stretch rate is small enough, almost all the water mist evaporates within the flame zone. On the other hand, for high stretch rate case, large mist droplets pass through the flame zone and can reach the stagnation plane. However, no oscillatory motion was found around the stagnation plane. Critical stretch rate at extinguishment decreases monotonously with the mass fraction of water mist independently of the mist diameter within the range of D₃₂ from 10 μm to 60 μm. On the other hand, with increase in the surface area parameter, the critical stretch rate at extinguishment decreases rapidly and becomes less sensitive at large surface area parameter, of which tendency is qualitatively in good agreement with theoretical predictions. For a constant surface area parameter, the critical stretch rate decreases with mist diameter because the mass fraction of water mist should increase in proportion to the mist diameter to keep the surface area parameter constant. When the water mist evaporates completely in the flame zone as in the present study, the mass fraction of the water mist is the dominant factor for fire extinguishment, rather than the surface area parameter. Therefore, an appropriate combination of stretch rate and water mist mass fraction should be provided to suppress effectively a given fire with a small amount of water mist.     

蚌埠市淮河南岸某高层建筑CFG桩复合地基应用探讨

以淮河南岸一级阶地某高层建筑采用CFG桩复合地基工程实例,通过利用工程地质参数复核计算、静载荷试验、沉降观测等验证资料,来探讨说明CFG桩复合地基在该区高层建筑使用的安全适用性。     

Single‐lumen tunneled catheter: An old but useful option

We report a case of long‐term uneventful catheter use in a patient with previous recurrent vascular access dysfunction and infection. A single‐lumen tunneled catheter was inserted into the left internal jugular vein after a failed attempt of dual‐lumen permanent catheter placement. The follow‐up since device implantation has exceeded 5 years without any complications related to vascular access.     

Optimized microwave excitation probe for general application in NDT of wall thinning in metal pipes of arbitrary diameter

Generalized approaches to developing a microwave NDT for flaws inside an arbitrary diameter pipe through optimizing a microwave-exciting probe were investigated. A microwave probe obtained from a parameter-optimizing scheme based on transmission characteristics is proposed. Three-dimensional finite element simulation of five microwave probes indicates that a larger optimization parameter enables reduced microwave reflection, as well as improved single-mode propagation inside the pipe as compared with conventional probes. Experimental verification, using straight brass pipes of various diameters confirmed that the optimized microwave probe exhibits a larger signal-to-noise ratio for internal flaws when compared with conventional probes, thereby validating the new optimization parameter.     

Digital Microfluidics for Manipulation and Analysis of a Single Cell

The basic structural and functional unit of a living organism is a single cell. To understand the variability and to improve the biomedical requirement of a single cell, its analysis has become a key technique in biological and biomedical research. With a physical boundary of microchannels and microstructures, single cells are efficiently captured and analyzed, whereas electric forces sort and position single cells. Various microfluidic techniques have been exploited to manipulate single cells through hydrodynamic and electric forces. Digital microfluidics (DMF), the manipulation of individual droplets holding minute reagents and cells of interest by electric forces, has received more attention recently. Because of ease of fabrication, compactness and prospective automation, DMF has become a powerful approach for biological application. We review recent developments of various microfluidic chips for analysis of a single cell and for efficient genetic screening. In addition, perspectives to develop analysis of single cells based on DMF and emerging functionality with high throughput are discussed.     

Data-driven model reduction-based nonlinear MPC for large-scale distributed parameter systems

Model predictive control (MPC) has been effectively applied in process industries since the 1990s. Models in the form of closed equation sets are normally needed for MPC, but it is often difficult to obtain such formulations for large nonlinear systems. To extend nonlinear MPC (NMPC) application to nonlinear distributed parameter systems (DPS) with unknown dynamics, a data-driven model reduction-based approach is followed. The proper orthogonal decomposition (POD) method is first applied off-line to compute a set of basis functions. Then a series of artificial neural networks (ANNs) are trained to effectively compute POD time coefficients. NMPC, using sequential quadratic programming is then applied. The novelty of our methodology lies in the application of POD's highly efficient linear decomposition for the consequent conversion of any distributed multi-dimensional space-state model to a reduced 1-dimensional model, dependent only on time, which can be handled effectively as a black-box through ANNs. Hence we construct a paradigm, which allows the application of NMPC to complex nonlinear high-dimensional systems, even input/output systems, handled by black-box solvers, with significant computational efficiency. This paradigm combines elements of gain scheduling, NMPC, model reduction and ANN for effective control of nonlinear DPS. The stabilization/destabilization of a tubular reactor with recycle is used as an illustrative example to demonstrate the efficiency of our methodology. Case studies with inequality constraints are also presented.     

Two‐Parameter Continuation and Bifurcation Strategies for Oscillatory Behavior Elimination from a Zymomonas mobilis Fermentation System

Two‐parameter continuation and bifurcation analysis strategies were applied to deal with the oscillatory phenomena of a Zymomonas mobilis ethanol fermentation system. A structured verified non‐linear mathematical model considering the physiological limitations of microorganisms for a single continuous fermenter for ethanol production using Z. mobilis was built to identify the Hopf bifurcation (HB) points, which indicate the oscillatory behavior, using the inlet substrate concentration and the dilution rate as bifurcation parameters. The path of the HB points can be determined with different controlling operating parameters. It was found that with the addition of a small amount of cells or ethanol to the feed stream or by increasing the dilution rate, the oscillations could be eliminated and steady‐state behavior was attained. Using a two‐parameter continuation strategy, the Z. mobilis fermentation system could operate at steady state without oscillatory behavior.     

Achieving Efficient Alkaline Hydrogen Evolution Reaction over a Ni5P4 Catalyst Incorporating Single-Atomic Ru Sites

Developing efficient electrocatalysts for alkaline water electrolysis is central to substantial progress of alkaline hydrogen production. Herein, a Ni₅P₄ electrocatalyst incorporating single-atom Ru (Ni₅P₄-Ru) is synthesized through the filling of Ru³⁺ species into the metal vacancies of nickel hydroxides and subsequent phosphorization treatment. Electron paramagnetic resonance spectroscopy, X-ray-based measurements, and electron microscopy observations confirm the strong interaction between the nickel-vacancy defect and Ru cation, resulting in more than 3.83 wt% single-atom Ru incorporation in the obtained Ni₅P₄-Ru. The Ni₅P₄-Ru as an alkaline hydrogen evolution reaction catalyst achieves low onset potential of 17 mV and an overpotential of 54 mV at a current density of 10 mA cm^-2 together with a small Tafel slope of 52.0 mV decade^-1 and long-term stability. Further spectroscopy analyses combined with density functional theory calculations reveal that the doped Ru sites can cause localized structure polarization, which brings the low energy barrier for water dissociation on Ru site and the optimized hydrogen adsorption free energy on the interstitial site, well rationalizing the experimental reactivity.